Kuzovenko V. Complexation of copper (II) on the surface of silika gels activated simultaneously with N-, S- containing ligands

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0405U001700

Thesis Registration Form

0405U001700.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

18-04-2005

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

Complexation of copper (II) on the surface of silika gels activated simultaneously with N-, S- containing ligands. The thesis is devoted to the experimental investigation of copper(II), cobalt (II) and nickel (II) adsorption on the surface of biligand chemically modified silica gels containing aminopropyl (ethylendiamine) and mercaptopropyl groups in various molar ratios. The composition of adsorption complexes has been established using methods of EPR, electron and luminescence spectroscopies. Cu(II) ions are coordinated with sulfur-containing ligands or are located in [NO]but not in [NS] surrounding on the surface of biligand amino- and mercaptopropyl chemically modified silica gels. It may be caused by various location of amino- and mercaptopropyl groups on the silica gel surface, namely gorisontal to the silica gel surface placing for aminopropyl groups, and vertical placing - for mercaptopropyl groups.

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Files

Dissertacija-Висновки.doc

Dissertacija-Вступ.doc

Dissertacija-Змист.doc

Dissertacija-Лит огляд.doc

Dissertacija-Розд 2.doc

Dissertacija-Розд 3.doc

Dissertacija-Розд 4.doc

Dissertacija-Розд 5.doc

Dissertacija-Розд 6.doc

Dissertacija-Список використаних джерел.doc

Dissertacija-Умов познач.doc

aref.doc

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