Tsygankov S. Cluster of cobalt Co3(?3-C-X)(CO)9 - stabilizers of oxidation of organic compounds

Clusters of a cobaltous in reactions with free radicals at oxidation of organic compounds (including - petroleum derivatives and polymers). Researches of trinuclear clusters of a cobaltous as stabilizers of oxidation of organic compounds. A volumetric method on gasometric installation; antitwilight properties of clusters of a cobaltous by 4 spherical machine of abrasion. It is shown, that the investigated clusters of a cobaltous catalyticly break off circuits of oxidation behind reactions-NHX-p-group of ligand with peroxides and alkils radicals. It is established, that clusters of a cobaltous are multifunctional front gardens to mineral oil (improve antioxidative and antitwilight properties). Received quantitative results have applied interest for synthesis and the directed choice the metallclusters stabilizers of oxidation of organic materials. Sphere of use - petrochemistry.