Lapandin A. Aryl(heteryl)acyloines. Synthesis and properties

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0405U002872

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

09-06-2005

Specialized Academic Board

Д 26.217.01

Institute of Organic Chemistry NAS of Ukraine

Essay

Paper is devoted to synthesis of new unsymmetrical benzoins [alpha]-series with the hydroxyalkylation of electron rich benzenes and heterocycles (pyrrole, indole, furan) with arylglyoxals and [beta]-series with the isomerization of [alpha]-benzoins in basic media and to studying of reaction ability of isomeric benzoins. Opportunity of functionalization of unsymmetrical benzoins with defending and orientating N,N-dimethylhydrazonomethyl group are shown. That has allowed to obtain benzoins with nitrile, aldehydic groups in the heterocyclic rest and their derivative.

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