Furman O. Reactions of intersphere substitution and oxidation-reduction in bysdiamine cobalt(III) complexes

Object - reactions of intesphere substitution and oxidation-reduction. The purpose - establishment of a sequence the processes of intersphere substitution and oxidation-reduction in solid stat and in solution of bysdiamine complexes of cobalt(III). Metods - the chimical analysis, DTA and thermogravimetrucal analysis, pH-measuring, potentiometric titratio. for the first time it is synthesized 6 new complexes.The new quantitative information on processes aquatation of halogen-aqua and dihalogenide complexes of cobalt(III) is received. For bysdipyridil complexes of cobalt(III) it is established, that presence in external sphere of a complex NO3 and ClO4-ions essentially reduces oxidizing properties of cobalt(III). The sphere of use is inorganic chemistry.