Yevdokymenko V. Isopropanol Obtaining over Proton Conductive Catalytic Membranes

Propene hydration reaction. Establishment of conformities to the law of propene hydration in the stream of hydration protons on membrane catalysts. Running and membrane methods of study of reaction, gaz-chromatography analysis, determination of proton conductivity of catalytic membranes. The hydration process was carried out in the developed membrane-catalytic reactor having reactionary volume formed with two proton-conductive membranes based on perfluorosulfonated cationic resins. Both the model of proton transport through membrane foil and the structure of Bronsted active sites in propene hydration conditions were proposed. High membrane proton conductivity in conditions of water fair quantities, dehydrated ability of proton and its relation with catalytic activity are explained by the proposed structures. Sphere of use - petrochemistry.