Tokaryk G. A determination of concentration of macromolecule crosslinks and scissions from kinetics of gel-formation in a polymer

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0406U000052

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

15-12-2005

Specialized Academic Board

Д 26.179.01

Institute of Macromolecular Chemistry of NAS of Ukraine

Essay

The new method of treatment of sol-gel analyse data in logarithmic-logarithmic coordinates has been proposed. The method is applicable for determination of crosslinking extent in polymers with any initial MWD. The new method has been applied to the real processes of polyethylene modification: radiation crosslinking in presence of acetylene; photochemical crosslinking in presence of aromatic and volatile photo-initiatiors as well as peroxide-mediated crosslinking of PE.

Files

Similar theses