Korobko S. Synthesis, physical-chemical properties, application in molecular design of new antimony containing clathrochelates Fe(II)

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0406U000843

Thesis Registration Form

0406U000843.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

23-02-2006

Specialized Academic Board

Д 26.218.01

V.I. Vernadskii Institute of General & Inorganic Chemistry NAS of Ukraine

Essay

Macrobicyclic tris-dioximates with antimony triorganyl capping fragments were synthesized first. The lacunar complex containing one capping group was synthesized first. The antimony containing clathrochelates are able to replace with capping groups stepwise. The new general method of synthesis of axial nonsymmetrical complexes was created. The method of synthesis of the poly nuclear complexes by the way of stepwise growth macrobicyclic chain was developed. First the hybrid complexes that contain fragments of phthalocyanine and clathrochelate in a molecule were obtained.

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Files

Diss1.doc

Diss1.doc

aref.doc

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