Plokhotnichenko A. Hydrogen-bonded and van-der-waals complexes of pyrimidine and benzene derivatives in argon and neon matrices

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0406U004326

Applicant for

Specialization

  • 01.04.14 - Теплофізика та молекулярна фізика

10-10-2006

Specialized Academic Board

Д64.175.03

Essay

Molar integral absorption coefficients have been determined for IR-spectral bands of molecules isolated in matrices and for the most characteristic bands of the complexes. The dependence of the number of monomers and H-bonded complexes on the concentration of the substance in the matrix has been determined, and the role of impurity molecule diffusion in the complex formation has been ascertained. The structures of the complexes and the influence of matrix invirontment on there energy have been determined.

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