Stolyarenko V. Synthesis, structure and properties of binuclear cluster rhenium(III) compounds with phosphatic ligands

3. Object: synthesis, structure, properties of cluster Re26+ de-rivatives with phosphatic ligands. Aim: synthesis and deter-mination of a structure and physicochemical properties binu-clear cluster compounds of rhenium(ІІІ) with phosphatic lig-ands. Research methods: the element analysis, IR and elec-tronic spectroscopy, X-ray crystal analysis, thermogra-vimetric, conductometry, potentiometry. The new methods of synthesis of complexes dirhenium(III) with coordinated phosphatic groups were developed. It has been allowed to receive 18 coordination compounds of 3 structural types. 16 compounds were obtained at first. The structure and compo-sition of obtained compounds were determined by the some methods. Transmutations phosphatic derivative of dirhe-nium(III) in conditions of contesting coordination at first were studied. The stability augmentation of the synthesized compounds to hydrolysis was established. Package research of thermal behaviour of complexes containing cluster Re26+ and phosphatic ligandswas realized at first. The stages of thermal decomposition of obtained compounds was estab-lished. Some kinetic parameters of thermal decomposition of studied compounds were calculated at first. Availability of further examination of different views of bioactivity of this class complexes. Sphere of use: coordination and bioinor-ganic chemistry, medicine.