Komarchuk V. Crystal engineering of the three-dimensional coordination polymers with microporous framework based on 4,4'-bipyrazolyls

The thesis is devoted to the development of approaches for the synthesis of a target three-dimensional coordination polymers with microporous frameworks based on two-dimensional metal-organic {М(L)2}n (L = 4,4'-bypirazolyl (bpz), 3,3',5,5'-tetramethyl-4,4'- bypirazolyl (Me4bpz)) layers by pillaring ?-SO42-, SeO42-, SiF62-, C2O42-, S2O62-, Mo8O264- anions. The approach for the construction of rare 5-connected three-dimensional metal-organic framework, by means of blocking sixth potential structure-formation bond in octahedral environment of metal, was introduce: coordination polymers with two new 5-connected topology types was obtained. The first microporous (8?) coordination polymers with unprecedented framework of hexagonal tungsten bronzes topology was obtained. Reversible adsorption of CH2Cl2 by [M(Me4bpz)2S2O6] demonstrated a zeolite-like behaviour of coordination polymers.