Koryakina E. Colloidal-chemical metamorphism regulations of laminar silicates and carbonates under the influence of man-caused factors.

The Dissertation is devoted to study of colloidal-chemical metamorphism regulations of laminar silicates and carbonates under the influence of man-caused factors in the systems of "atmosphere-water reservoir-water reservoir base" type. Basic factors, which influence on dynamics and direction of clay-carbonate dispersions metamorphism development in open dissipative ecosystems. Main self-organization regulations in clay-carbonate dispersions under the influence of "acid" atmosphere gases and acid metallurgic slags in conditions of its contacting with mineralized water were studied. It was established that in the systems of "atmosphere-water reservoir-water reservoir base" type the dominating role in metamorphism initiation of clay-carbonate breeds belongs to interphase colloidal-chemical interactions, which run on "solid phase/liquid" interface. Specified colloidal-chemical model of interactions between silicate-carbonate dispersions, mineralized water and "acid" atmosphere gases was proposed. Main chemical and colloidal-chemical regulations of silicates and metallurgic slags while concentrating, condensation and further solidification or metamorphic transformation of dispersions on their base were investigated. Water reservoir base mine waters mudding technologies and methods of alumosilicate and slag based mineral hardening dispersions physical-chemical properties handling were found and successfully applied.