Tkachova N. Synthesis and thermolysis of solid solutions of manganese(II), cobalt(II), zinc hydrated diphosphates.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0409U000711

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

12-02-2009

Specialized Academic Board

Д 26.218.01

V.I. Vernadskii Institute of General & Inorganic Chemistry NAS of Ukraine

Essay

For the first time five solid solutions of manganese(ІІ), cobalt(ІІ), zinc hydrated diphosphates of composition: Mn2-xZnxP2O7·5H2O, Мn2-хCoхP2O7·5H20, Co2-хМnхP2O7·6H2O, Co2-хZnхP2O7·6H2O, Zn2-хCoхP2O7·5H2O are synthesized. Their homogeneous domain and features of formation are established. The thermolysis for the first time obtained solid solutions is investigated. Opportunity of their use as rust inhibitors, fertilizers, a drug for processing seeds and for processing a silk-worm eggs was shown.

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