Marshalok O. Peculiarities of methyl-alpha-alkylsubstituted acrylates copolymerization

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0409U002338

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

21-04-2009

Specialized Academic Board

Д 26.001.25

Taras Shevchenko National University of Kyiv

Essay

Peculiarities of methyl-alpha-alkylsubstituted acrylates copolymerization with methylmethаcrylate in bulk and with mеthylacrylate in еmulsion have been established. Copolymerization deceleration is caused by low rate of monomers addition to macroradicals with terminal methyl-alpha-alkylacrylates links. Effective initiation of emulsion copolymerization is realized by sulfate anion-radical. Physico-chemical and physico-mechanical properties of оbtained copоlymers and emulsion films have been determined.

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