Moroz O. Mono- and polynuclear lanthanides and copper containing coordination compounds based on phosphorylated sulfamides

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0409U003830

Thesis Registration Form

0409U003830.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

26-10-2009

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The dissertation is devoted to synthesis, structural studies and properties of mono- and polynuclear lanthanide- and copper(II)- containing complexes based on phosphorylated sulfamides. The possibility of using unsaturated lanthanide complexes based on phosphorylated ligands as building blocks for obtaining of the 3d-4f heterobinuclear complexes has been demonstrated. For the complexes {Na[Yb(L1)4]}n (1), [Yb(L1)3·phen] (2) and [Yb(L1)3·dipy]·Н2О (3) intensive lifetime in IR region was recorded and the structure of energy sublevels for the ground and excited states of Yb3+ ion was determined.

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Files

avtoreferat_end.doc.pdf

moroz_ov_disser.pdf

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