Smalius V. Synthesis and properties of 4-replaced 1-arenesulfonyl-2-butenes and 1-arenesulfonyl-1,3-butadienes

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0409U003985

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

26-10-2009

Specialized Academic Board

Д 35.052.01

Lviv Polytechnic National University

Essay

The dissertation is devoted to synthesis and exploring of properties of 4-replaced 1-arenesulfonyl-2-butenes and 1-arenesulfonyl-1,3-butadienes. Development of new methods of synthesis of 4-functionally replaced 1-arenesulfonyl-2-butenes/. It is was found out that in the reaction of chloroarylation, 1-arenesulfonyl-1,3-butadienes interact with arenediazonium chlorides, arenediazonium tetrachlorocuprates(II) and 1-arene-3,3-dymethyl-1-triazenes, making up products of adjunction of aromatic radicals and chlorine atoms according to the double bond, the most distant from arenesulfonyl group.

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