Mykhaylychenko S. Perfluoroketene dithioacetals and perfluoroketene-N,S-acetals in the synthesis of fluorinated acyclic and heterocyclic compounds.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0409U004952

Thesis Registration Form

0409U004952.pdf

Applicant for

Mykhaylychenko Sergiy Sergiyovich

Specialization

02.00.03 - Органічна хімія

Date of defense

22-10-2009

Specialized Academic Board

Д 26.217.01

Institute of Organic Chemistry NAS of Ukraine

Essay

The dissertation is devoted to the synthesis of fluorinated unsaturated lactams and pyridazinones and to the investigation of chemical properties of perfluoroketene-N,S-acetals including possibilities of their synthetic applications. New convenient methods of the synthesis of fluorinated lactams and pyridazinones derivatives were developed. It was found that the outcome of oxidation reaction of perfluoroketene-N,S-acetals depends on the nature of the oxidizing agent. It was shown that chlorination of perfluoroketene-N,S-acetals with sulfuryl chloride results in the formation of amides of chloropolyfluoroalkanecarboxylic acids.

Thesis supervisor

Shermolovich Yuriy Grigorievich

Official opponents

Харченко Олександр Васильович
Костюк Олександр Миколайович

Files

diser.doc

реферат.doc

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