Khovanets' G. Kinetic regularities of photoinitiated copolymerization of mono- and di(меth)аcrylates till high conversions

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0409U005355

Thesis Registration Form

0409U005355.pdf

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

09-11-2009

Specialized Academic Board

Д 35.052.01

Lviv Polytechnic National University

Essay

The kinetic regularities of stationary photoinitiated copolymerization of mono- and di(mеth)аcrylates till high conversions depending on nature and functionality of comonomers, composition of systems, photoinitiator concentration and UV-radiation intensity have been investigated by laser interferometry. The kinetic regularities of mеthacrylate and acrylate macroradicals decay in polymer matrices of a different nature have been studied by ЕSR-spectroscopy. The kinetic models of linear and 3-D copolymerization of methacrylates till high conversions have been derived. The kinetic model of copolymerization at the linear chain termination has been derived as well.

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Files

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