Kliachyna M. Amides of calixarene carboxylic acids. Synthesis and properties.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0410U000277

Thesis Registration Form

0410U000277.pdf

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

21-01-2010

Specialized Academic Board

Д 26.217.01

Institute of Organic Chemistry NAS of Ukraine

Essay

The preparative methods of synthesis of calixarenes bearing N-chalconeamide groups on the narrow rim have been developed. I was shown that chalconeamide derivatives of calix[4]arene modulate Ca2+ accumulation in the smooth muscle cells. An approach to the synthesis of a series of the optically pure inherently chiral calixarenes (carboxylic acids, amides, and amines) has been developed. It has been shown that calixarene carboxylic acids discriminate enantiomers of chiral amines. The catalytic activity of inherently chiral calixarene amine has been investigated in the asymmetric Michael addition and Pudovik reaction.

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Files

KLIACHYNA-AVTOREFERAT.doc

Клячина-дисертація.doc

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