Boryk V. Crystal-chemistry of point defects and their complexes and thermoelectric properties of solid solutions on the basis of PbTe, SnTe, GeTe.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0410U000779

Applicant for

Specialization

  • 02.00.21 - Хімія твердого тіла

12-03-2010

Specialized Academic Board

К 20.051.04

Essay

For the first time are offered the crystal-quasichemical formulas, calculations and experimental researches dependences concentration of point defects, free carriers and Holl's concentration of charge from value of a deviation from stoichiometry and structure in Pb-М-Te (М = Gа In, Tl, Cr, Мn), on the basis of which established defect subsystem and nature of doping and mechanisms formations of solid solutions also conditions of realization thermodynamic р-n-transition are certain.

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