Posternak A. Bis(perfluoroalkylsulfonylimino)derivatives of sulfur

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0410U001084

Thesis Registration Form

0410U001084.pdf

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

24-12-2009

Specialized Academic Board

Д 26.217.01

Institute of Organic Chemistry NAS of Ukraine

Essay

Trimethylsilyl esters of bis(perfluoroalkylsulfonylimino)trifluoromethanesulfonic acids have been prepared. On the base of the NMR 29Si chemical shifts acidity of new superacids was estimated. N-Methyl and N-ethyl derivatives of bis(trifluoromethylsulfonylimino)trifluoromethanesulfonic acid (BTISA) were prepared by alkylation of BTISA or its silver salt. Method of nucleophiles' alkylation in the presence of silver salt of BTISA has been devised. Тhe thermal decomposition of aryldiazonium salt of BTISA was studied. BTISA may exhibit high catalytic activity in Friedel-Crafts acylation and cyclization, aminolysis of epoxides.

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Files

Автореферат Постернак.doc

Дисертація Постернак.doc

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