Khomenko D. Synthesis and structure of some d-metal complexes of triazolilacetic acid derivatives.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0410U001859

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

29-03-2010

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The dissertation is devoted to synthesis, spectroscopic and X-ray structural investigations of some d-metal complexes of triazolil acetic acid derivatives. The new synthetic procedures based on the interaction of metal salts with triazol-containing ligands in the nonaqueous solutions (methanol, dimethylformamide, acetonitrile) have been elaborated and 17 new coordination compounds were prepared using those. The crystal structures of the 8 new complexes have been determined by X-Ray crystallography. The compounds were studied by means of IR-, UV/Vis, EPR-spectroscopy, NMR-spectroscopy, mass-spectrometry.

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