Nikitin S. The coordination compouns of 3d-metals with 2-amino-4(5H)-ketoderivatives of pyrrole and thiophen

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0410U001860

Thesis Registration Form

0410U001860.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

29-03-2010

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The dissertation is devoted to investigation of coordination abilities of 2-amino-4(5H)-keto derivatives of pyrrole and thiophen towards 3d-metall ions. The synthetic methods for preparation of ligands and 3d-metal complexes were developed. It was selected in the individual state and identified 38 new mononuclear coordination compounds of nickel(ІІ), cobalt(ІІ), zinc(ІІ) and copper(ІІ). It was found grounding on the IR, UV/Vis, EPR and NMR spectroscopic studies, that complexes of 3d-metal ions with neutral form were obtained in the case of the use of metal chlorides as reactants, while the complexes with deprotonated form of ligands were obtained at the use of metal acetates.

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Files

Avtoreferat Nikitin.pdf

disertation.pdf

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