Loboyko V. Carbon oxide conversion on copper-zinc-aluminium catalyst at low ratio water vapour : dry gas

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0410U004868

Applicant for

Specialization

  • 05.17.01 - Технологія неорганічних речовин

18-11-2010

Specialized Academic Board

Д 64.050.03

National Technical University "Kharkiv Polytechnic Institute"

Essay

A research object is a process of low temperature conversion of oxide of carbon (ІІ) by aquatic steam of production of ammonia. A research purpose is an improvement of technology of low temperature conversion of oxide of carbon (on the catalyst of brand of K-СO) for diminishing of expense of aquatic steam in the production of ammonia. Research methods and apparatus - theoretical: thermodynamics calculations, including equilibrium of low temperature conversion CO with the use of method of the resulted states; experimental: kinetics of renewal of catalyst and kinetics of conversion of K-СO on the catalyst of K-СO - in integral, near to isothermal reactor to the running laboratory setting; khromatograficheskiy analysis of gas mixtures; by standard methods is chemical composition, closenesses and steam descriptions of catalyst; statistical methods of treatment of results. Theoretical and practical results - the technological parameters of the low temperature stage of conversion СО are offered of the production of ammonia with the mionectic expense of aquatic steam. Novelty - influence of correlation of aquatic steam to dry gas and oxide of carbon (IV) is set on an equilibrium and kinetics of low temperature conversion СО, kinetic equalization of this reaction is developed on the copper-zinc-aluminium catalyst of K-СO. Degree of introduction - job performances are passed to close "Severodonetsk azot association" for the feasability study of applying in industry of ammonia; introduction in the educational process of NTU "KHPI". Industry of the use - in technology of production of ammonia, research and project institutes and in an educational process.

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