Kudina O. Amphiphilic comb-like copolymer synthesis for micellar self-assembles and silver nanoparticles fabrication

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0411U000201

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

04-01-2011

Specialized Academic Board

Д 35.052.01

Lviv Polytechnic National University

Essay

Thesis is dedicated to synthesis of novel amphiphilic comb-like copolymers (or with peroxide groups), with controlled ratio of hydrophilic and lipophilic fragments, via polymer-analogical transformations of binary maleic anhydride copolymers and 1-olefins or octylmethacrylate. The specialties of acylation by polyanhydride alcohols were established. Microphase segregation abilities of amphiphilic comb-like copolymers and their ability to form self-assembled micellar structures were studied by the means of colloid-chemical and X-ray scattering studies of copolymer solution. These self-assembled micellar structures were utilized as nanoreactors for preparing silver nanoparticles.

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