Golovko-Kamoshenkova O. Reactions of 1,3,5-tris(fluorosulfonyl)benzene with nucleophilic reagents and its anionic sigma-complexes

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0411U001846

Thesis Registration Form

0411U001846.pdf

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

24-03-2011

Specialized Academic Board

Д 26.217.01

Institute of Organic Chemistry NAS of Ukraine

Essay

The dissertation is devoted to the investigation of reactions of 1,3,5-tris(fluorosulfonyl)benzene (TFSB) with various nucleophilic reagents. It was shown that depending on the nature of nucleophile its attack may be directed either on the sulfonyl centers of TFSB or on the free position of its aromatic ring. New compounds - products of fluorine atom substitution in one, two or three groups SO2F of TFSB have been synthesized. It was shown that interaction between TFSB and soft nucleophiles in DMSO or DME leads to the anionic sigma-complexes formation.

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Files

aref.doc

дисертація.doc

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