Pavlishchuk A. Synthesis, structure and physico-chemical properties of the extra-coordinated systems based on the metallacrowns

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0412U000382

Thesis Registration Form

0412U000382.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

27-02-2012

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The thesis concerns the studying of possibility of porous compounds creation on the basis of 12-metallacrown-4 (12-МС-4) [Cu5(ahpha)4]2+ and 15-metallacrown-5 (15-МС-5) [LnCu5(GlyHA)5]3+ (Ln3+ = Pr3+, Nd3+, Sm3+, Eu3+, Gd3+, Dy3+ or Ho3+) polynuclear complexes. 42 new complexes were obtained; structures of 41 compounds were determined by X-Ray. The sorption properties of porous compexes were studied. Magnetic properties of the obtained complexes were investigated and approaches of 15-МС-5 magnetic properties simulation were developed. Four complexes are SMMs.

Read more

Files

Автореферат.pdf

Дисертація.pdf

Similar theses

0524U000154

Tatiana Kiose

Natural aluminosilicates and carbon materials functionalized with d-metal compounds. Synthesis, properties, application.

0424U000102

Nataliya Chorna

Interaction of components in the systems {La, Gd}–{Mn, Fe}–Zn (phase equilibria, crystal structure and some properties of compounds)

0523U100191

Grygorii S. Dmytriv

Interaction of lithium with d-metals and p-elements of III-V groups

0522U100046

Lysenko Andrii B.

Coordination polymers based on 1,2,4-triazole containing ligands

0521U101843

Terebilenko Kateryna Volodymyrivna

Complex oxides based on uni-, bi- and trivalent metals with tetrahedral anions: synthesis, structure and properties