Kovalenko O. Reactions of molybdenum and tungsten alkoxides, containing metal-metal and metal-ligand multiple bonds with low-coordinate phosphorus compounds

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0412U001291

Thesis Registration Form

0412U001291.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

30-01-2012

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The thesis is devoted to the synthesis, structure and properties analysis of new complexes. These complexes were obtained in reactions of (Me3Si)2NPNSiMe3, (Me3Si)2NPNtBu, (Me3Si)2NPS(NtBu), (Me3Si)2NP(NSiMe3)2 with molybdenum and tungsten alkoxides{(iPrО)3МM(ОiPr)3; NM(OR)3; O=M(OR)4, M= Mo, W, R = tBu, iPr, Et}. Obtained complexes were characterized by NMR spectroscopy, elemental and single X-ray analysis. Altogether the 25 new compounds were synthesized.

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