Yatskin M. Synthesis, structure and properties ofheterometallic phosphates based on alkali, bi- and trivalent metals

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0412U006709

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

17-12-2012

Specialized Academic Board

Д26.001.03

Essay

The thesis is devoted to investigation of crystal formation insodium and potassium phosphate's melts containing combinations of bi- and trivalent metals. The formation conditions of complex phosphates from self-flux systems MI2O-P2O5-MIІI2O3 (YF3)-MIIO (MI- Na, K;MIIІ - Al, Fe, Ga, Bi; MII - Mg, Mn, Co, Ni, Cu, Zn) have been discovered.Heterometallic compounds Na4MІІМІІІ(PO4)3 and KMIIxFeII1-xFeIII(PO4)2 (MII - Mg, Ni, Cu (0 х ? 1)and its solid solutions,Na3,35Ni2,35МІІІ0,65(P2O7)(PO4)2 (MIII - Al, Ga), K4MIIFe3(PO4)5 (MII - Mg, Co, Ni) have been obtained.

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