Levkov I. Reactivity of 1-aminoisoindole, its derivatives and analogues in reactions with dienophiles in homogeneous and structural media.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0413U003983

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

26-03-2013

Specialized Academic Board

Д 26.001.25

Taras Shevchenko National University of Kyiv

Essay

The dissertation is devoted to studying of reactivity of 1-aminoisoindole, its derivatives and analogues in reactions with dienophiles. Due to the Curtin - Hammett principle, first isoindoles, that mainly located in isoindoline tautomeric form, were undergo the reactions with maleimides. Study of the reactivity of amphiphilic derivatives of 1-aminoisoindoles in homogeneous and structural media were made. The catalytic role of aggregated media in the reactions with cyclic dienophiles was shown. Convenient methods of synthesis of fluorescent derivatives of 4-amino-benzo[f]isoindole are proposed.

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