Kazmirchuk N. Features of structure and properties of the activated polymer including compositions

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0414U000393

Applicant for

Specialization

  • 05.23.05 - Будівельні матеріали та вироби

25-02-2014

Specialized Academic Board

Д 41.085.01

Odessa State Academy of Civil Engineering and Architecture

Essay

Object of study is polymer-based composition on the base of the epoxy binder, fillers and activated rational matrix fractal resonators; goal - improving physical and technical properties of polymer compositions directed by the organization of their structure by internal, external and integrated activation; methods - the organization structure of model systems was carried out using simulators particles dispersed phase and the dispersion medium; volumetric deformation magnitude was determined by reducing the geometrical volume of hardened samples, designed in the form of cylindrical rings by means of special sensors, of physical and mechanical properties, modulus of elasticity and fracture toughness of the polymer compositions was determined according to standard techniques; erosion of the initial defect solidified samples was evaluated using the coefficient of technological damage; statistical analysis of experimental results and optimization of polymer compositions activated composites was carried out using the apparatus of mathematical planning of the experiment (COMPEX); results - theoretically substantiated and experimentally confirmed the possibility of managing the organization of cluster structures of filler particles in the polymer-containing composition as complex dynamic open systems by changing the external electromagnetic influences using fractal-matrix resonators; The effect of activation methods adopted by the magnitude and kinetics of the initial volume strain characteristics as polymer composites, indirectly reflecting the change in the parameters of their structure under the influence of controlling factors; the influence of internal, external and integrated activation on fracture toughness, physical, mechanical and deformation characteristics of polymer compositions is determine; experimentally was obtained complex of statistical models of separate and joint influence of internal and external factors on the properties of filled polymer composites, on which was recommended efficient way to activate them and identify rational formulations of excipients subject to regulatory requirements; introduced - by the manufacture of highly filled polymer coating self-leveling floor.

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