Ohar H. Synthesis macrophotoinitiators on the basis of cooligomers of the maleic anhydride

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0414U000754

Thesis Registration Form

0414U000754.pdf

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

12-03-2014

Specialized Academic Board

Д 35. 052. 01

Essay

The thesis is devoted to synthesis of the novel heterofunctional macrophotoinitiators on the basis of cooligomers of maleic anhydride with pendent either benzoin or 3-hydroxy-2-isopropoxy-1,2-diphenylpropan-1-one pieces. Macrophotoinitiators have been synthesized applying polymer-modification reaction grounded on the acylation of aromatic alcohols by the maleic anhydride cooligomers, that allows to incorporate controlled amount of the chromophore grouping into the structure of macromolecule. It is shown that obtained macrophotoinitiators are the effective initiators of radical polymerization and cross-linking reactions and can be applied for creation of the composite materials with enhanced mechanical properties.

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Files

Ohar_Disser.doc

aref.doc

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