Dehtiarenko A. The framework coordination polymers based on polyfunctional pyridazines

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0415U002402

Thesis Registration Form

0415U002402.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

02-06-2015

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The dissertation is devoted to synthesis and X-ray studies for metal complexes based upon polyfunctional pyridazine ligands. Crystal structures of coordination polymers involving Ag(I), Cu(I), Cu(II), Cd(II) and Co(II) ions reveal basic trends for coordination modes of the ligands. Cuprocyanide complexes provide a rare example for 4-coordination of cyanide and first example for p -coordination of cyanide towards Cu(I). The series of 1,3-bis(4-pyridazinyl)benzene complexes reveals an anion-selective assembly of discrete cationic capsules [(SiF6)2Cu2(1,3-dpph)4]2+.

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Files

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