Davydova Y. Poly- and Perfluoroalkoxy Derivatives of Carbonyl Compounds in Nitrogen-containing Heterocycles Syntheses

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0416U000790

Thesis Registration Form

0416U000790.pdf

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

24-03-2016

Specialized Academic Board

Д26.217.01

Essay

Dissertation is devoted to development of the fluoroalkoxy substituted nitrogen-containing heterocycles syntheses from fluoroalkoxylated polyfunctional carbonyl compounds and to investigation of chemical properties of synthesized heterocycles. Fluoroalkoxy derivatives of malonic dialdehyde, enaminones and bromoketones were synthesized. Such carbonyl reagents were used as starting compounds for construction of pyrazoles, isoxazoles, thiazoles and pyrimidines with fluoroalkoxy groups. It was shown that tetrafluoroethoxy substituent is resistant to acidic and alkaline media, catalytic hydrogenation and organomagnesium reagents action.

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Files

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dis.doc

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