Savatieiev O. P,P- and P,N-bidentate phosphine ligands for metalocomplex catalysis

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0416U001261

Thesis Registration Form

0416U001261.pdf

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

21-01-2016

Specialized Academic Board

Д 26.217.01

Institute of Organic Chemistry NAS of Ukraine

Essay

The thesis is devoted to the new methods of pyrrole, ferrocene and formamidines based P,P- and P,N-bidentate phosphine ligands synthesis. The catalytic activity of aforementioned ligands transition metal complexes was studied in cross-coupling and olefin polymerization reactions. It was shown that lambda5-phosphinines can be used as precursors for lambda3-phosphinine synthesis upon their reduction with lithium aluminium hydride or di(iso-butyl)aluminium hydride.

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Files

aref.doc

dis.doc

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