Kulai I. New heteroelement-based regulators for controlled radical polymerization: synthesis and reactivity

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0416U002706

Thesis Registration Form

0416U002706.pdf

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

14-06-2016

Specialized Academic Board

Д 26.001.25

Taras Shevchenko National University of Kyiv

Essay

The thesis is devoted to the synthesis and evaluation of new heteroelement-based regulators for controlled radical polymerization. Thirteen new organophosphorus and organotin RAFT agents were synthesized. In particular, triarylstannanecarbodithioates were considered for the first time as chain transfer agents for the RAFT polymerization. The efficiency of the synthesized compounds as chain transfer agents was confirmed by the use of model radical polymerizations.

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Files

aref.pdf

dis.pdf

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