Rad N. Investigation of reaction of 1-nitroethenes and substituted 2-nitrothiophens with active methylene compounds

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0416U004200

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

10-10-2016

Specialized Academic Board

Д.35.052.01

Essay

Dissertation is devoted to research the reactions of nitroethenes and 2-nitrothiophens with active methylene compounds, to find the regularities of their course and to expand the limits of application. The conditions of formation of 2 furanon oximes in the reactions of 2-aryl- and 2-hetaryl-1-nitroetenes with cyclic and noncyclic 1,3-diketones were clarified. New oximes of 2-thiophenon were synthesized in the reaction of 2-nitrothiophen and its derivatives with arylacetonitriles. The regularities observed for both reactions were compared and probable mechanisms were proposed.

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