Karpus A. Chiral calix[4]arenes with phosphorus-containing groups, using in asymmetric catalysis

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0417U000270

Thesis Registration Form

0417U000270.pdf

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

24-01-2017

Specialized Academic Board

Д 26.001.25

Taras Shevchenko National University of Kyiv

Essay

The thesis is devoted to the developing of effective methods for the synthesis of new class of inherently chiral phosphorus-containing calix[4]arenes, phosphines and phosphoric acids with a certain mutual arrangement of functional groups on the lower rim of the macrocycle, with potential catalytic activity. The optimal way fot the synthesis of phosphorus-containing calix[4]arenes by the stepwise substitution of the phenolic hydroxyls was developed in order to design inherently chiral calix[4]arenes with ABHH and ABCH replacement types at the lower rim of the macrocycle.

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Files

aref_Karpus_UKR.pdf

disser_Karpus_UKR.pdf

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