Stetsiuk O. Homo- and Heterometallic 3d-Metal Complexes with N- and N,O-donor Ligands: Synthesis, Structure and Properties

The thesis is devoted to the synthesis of homo- and heterometallic 3d-metal complexes with Schiff-base ligands and ligands, derivative of 1,2,4,5-tetrazine, investigation of their structure, physico-chemical and functional properties. The methods of synthesis for 30 new homo- and heterometallic complexes were proposed. Compounds were investigated by X-Ray, IR and EPR spectroscopy, mass-spectrometry and magnetochemistry. The formation of mono-, bi-, tri-, tetra- and hexanuclear complexes and compounds with polymeric structures was studied. It is shown that the synthesized compounds possess the catalitic activity in the reaction of photochemical water oxidation, exhibit antimicrobial and semiconducting properties, photovoltaic and photovoltaic properties in polymeric composites and can be used for the development of multifunctional materials of wide use.