Kovbasyuk L. Direct synthesis of the Cu/Pb heteronuclear complexes with aminoalcohols

The dissertation is devoted to development of a new approach to obtain heteronuclear complexes by direct synthesis. The interaction of copper powder with lead salts in non-aqueous solutions of aminoalcohols as well as aminoalcohol hydrochlorides has been studied and complexes with different Cu : Pb ratio have been obtained The new synthetic procedures to heteronuclear compounds have been elaborated and 63 novel Cu/Pb heteronuclear complexes have been prepared using those. The compounds were studied by IR-, EPR-spectroscopy, magnetochemistry and also tested for antitumour activity The crystal structures of the 12 new complexes have been determined by X-Ray single crystal analysis. Direct synthesis is shown to be a new promising area of research in chemistry of heteronuclear compounds.