Pashynnyk V. Dialkylaminofluorosulfuranes, polyfluoroalkoxyfluorosulfuranes, sulfonium and selenonium salts at their basis

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0500U000059

Thesis Registration Form

0500U000059.pdf

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

17-02-2000

Specialized Academic Board

Д 26.217.01

Institute of Organic Chemistry NAS of Ukraine

Essay

Synthesis and ivestigation of chemical properties of new type sulfuranes containing (,(,(-trihydropolyfluoroalkoxy radicals, dialkylamino-groups or fluorine atoms at tetra-covalent sulfur atom. Termal stability and reactions with electrophilic reagents are investigated. Synthesis methods for dialkylaminosulphonium and seleno- nium salts, triphenylsulphonium salts with fluorine-containing complex anions are elaborated. Methods of fluorine atom introduction into organic moleculs are elabora- ted. Fine organic synthesis, spectral and X-ray structural methods of ivestigation are used.

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