Grafov A. Synthesis, structure and properties of Ti, Zr and Hf metallocene co-ordination compounds with bridged alicyclic alcoholato-ligands

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0501U000029

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

25-01-2001

Specialized Academic Board

Д 26.218. 01

Essay

The thesis is devoted to investigation of Ti, Zr, Hf metallocene co-ordination compounds with bridged alicyclic ligands. New complexes were synthesised, their composition and structure were determined from joint data of modern NMR- and MIKE-spectroscopy, mass spectrometry techniques. A pathway was shown for design and creation of new substances - precursors for obtaining of coatings with controlled composition and properties, as well as catalysts for creation of polymers with consciously formed tacticity.

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