Voloshanovs'kyj I. Functional polymers on the basis of b-diketones and porphyrins.

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0501U000359

Thesis Registration Form

0501U000359.pdf

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

30-10-2001

Specialized Academic Board

Д 26.001.25

Taras Shevchenko National University of Kyiv

Essay

Fundamental regularities of the receiving homo- and copolymer diketones and porphyrins on the basis of radical polymerization of corresponding monomers process are determined. Participation of unsaturated fragment of chelates in complexes building process is shown. Copolymer diketone's complexes with Eu (III) have anomalously high luminescence intensity which makes it possible to use them as organic luminophores. Unsaturated cobalt (II) b-diketonates are used as bifunctional polymerization components (initiators and comonomers). Their application let us to get macroinitiators for the first time which can be used in polymer modification processes.

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