Amirkhanov V. Coordination chemistry of carbacylamidophosphates

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0502U000342

Thesis Registration Form

0502U000342.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

23-09-2002

Specialized Academic Board

Д26.001.03

Essay

The thesis is devoted to the investigation of coordination chemical properties of carbacyl-amidophsphate (CAPh) type ligands. 250 new compounds, including complexes with s-, p-, d- and f-metals were synthesized and investigated. For 45 CAPh compounds and their complexes the molecular and crystal structures were established. For CAPh ligands in the neutral form the phenomenon of intramolecular self-organization, determining design of coordination particle was revealed. It was demonstrated that unsaturated lanthanide tris-complexes may be used as building blocks for supramolecular systems.

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