Shyvanyuk O. Functional calix[4]arenes and calix[4]resorcinolarenes in self-assembly and molecular recognition

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0505U000534

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

20-10-2005

Specialized Academic Board

Д26.217.01

Essay

Dissertation is devoted to development of general methods for selective functionalization of calix[4]-resorcinolarenes and calix[4]arenes at the wide rim of the macrocycles as well as to molecular design an investigation of the properties of new receptors, molecular capsules and self-assembling systems. A wide number of new calix[4]resorcinolarenes and calix[4]arenes have been obtained which bear at the wide rim of the macrocycle Н-donor, Н-acceptor and coordinating groups in various ratios. New highly stable hexameric hydrogen bonded capsules have been obtained, which are capable of including ionic and neutral guests in non-polar media

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