Tulskiy G. Anode processes on oxides of base metals in an electrochemical synthesis of mineral substances

The combined anodic processes on a surface of composition coverings on the basis of oxides of base metals in an electrochemical synthesis of mineral substances. Regularity of anodic processes of an electrochemical synthesis of mineral substances on PbО2/TiО2 and Со3О4/TiО2 coverings are installed. Development of scientific bases of creation DSA on the basis of oxides base metals with predicted catalyst properties, selectivity and passive hardness is executed. Methods of researches is the complex of physical and chemical and technological methods. The opportunity of creation of composition anodic materials on the basis of oxides base metals is theoretically proved and experimentally confirmed. For the first time by a method of thermolysis are gained PbО2/TiО2 and Со3О4/TiО2 covering DSA. Effect of composition and conditions of reception of anodic materials on their physical and chemical properties is installed. Technological parameters of processes of electrochemical synthesis H2S2O8, (NH4)2S2O8, NaIO4,NaClO are developed at use of the developed anodes instead of platinum and the RuO2. Anodes are introduced in oscillators of a solution of an available chlorine and in trial installations of an electrochemical synthesis of inorganic substances. Sphere of application: electrochemical synthesis of oxidizing agents, electrodialyz.