Samaryk V. Modification of polymer surfaces using polyperoxides

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0509U000489

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

03-07-2009

Specialized Academic Board

Д.35.052.01

Essay

This thesis is devoted to the development of theoretical and practical principles the synthesis of new type reactive polyperoxides and their utilization for polymer surface modification to impart special properties.Theoretical principles of the formation of polyperoxide nanolayer grafted to the polypropylene surfaces as well as the mathematical model that allows to evaluate and predict parameters of grafted nanolayer have been developed. It has been shown that peroxide groups of grafted nanolayer are able to initiate radical process of grafting.

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