Romenskiy O. Physical and chemical basics and development of technologies for heterogeneous catalyst synthesis and reduction by acoustic radiation

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0509U000731

Applicant for

Specialization

  • 05.17.01 - Технологія неорганічних речовин

26-11-2009

Specialized Academic Board

Д 64.050.03

National Technical University "Kharkiv Polytechnic Institute"

Essay

An object is technologies of synthesis and renewal of aktivity catalysts with the use of acoustic radiation. A purpose is development of physical and chemical bases and technologies of synthesis and renewal of activity of geterogen catalysts with the use of acoustic radiation. Methods are an atom-adsorbcion spectrophotometry, fiery photometry, spektrografiya, derivatografiya, porometriya, piknometriya, thermal desorption, rentgenometriya. Novelty - first taking into account the fundamental laws of thermodynamics and kinetics theoretical bases are developed and technologies of acoustic renewal of activity are offered for geterogennykh catalysts; first in theory grounded and the mechanism of acoustic preparation of geterogen catalysts of adsorption type, being based on the theory of sonars, is experimentally confirmed. Results - the new are developed, not having analogues in world practice, effective technologies of preparation of granular catalyst of production of vinilacetat; renewals of activity of the worked catalyst of synthesis of formaldehyde; renewals of activity and physical and chemical kharaktieristik catalyst of cleaning of CO2 from combustible connections of production of karbamid. A degree of introduction is industrial introduction of new technologies on ZAO "Severodoneckoe association allowed to get Nitrogen" actual economic effect in size of 10 060 511,00 Uah. Industry - in technology of neorganic matters and chemical industry, research institutes and in an educational process.

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