Hevus O. Functional surface active peroxides and monomers as reagents for obtaining reactive modifiers of surface

The thesis is devoted to the development of obtaining novel peroxides and monomers and the ways of their application for creating modifiers of surface and drug delivery systems. The way of synthesis of surface active peroxides, peroxide containing monomers, which involves linkage in different combinations of various types of peroxides, fragments of monomers with polymerizable properties and surface active units has been proposed. The reactive properties of bifunctional compounds in reactions of alkylation of hydroperoxides have been investigated for the first time. New classes of surface active monomers with lypophilic alkylic, fluoroalkylic, olygomethylsiloxanic and saccharide blocks and different types of hydrophilic blocks have been obtained. The obtained compounds have been shown to be capable of creating surface active modifiers of surface and surface modified polymeric and mineral colloids, as well as being high-performance drug delivery vehicles.