Kulinskii V. Asymmetry of the critical behavior of liquid systems

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0511U000773

Applicant for

Specialization

  • 01.04.14 - Теплофізика та молекулярна фізика

18-10-2011

Specialized Academic Board

Д 26.001.08

Taras Shevchenko National University of Kyiv

Essay

The description of the asymmetry effects in the critical behavior of the fluid systems is proposed. The explanation for a number of well-known facts of fluid system equilibrium is given. The relations between the thermodynamic potentials of these systems are obtained. The nonperturbative construction of the canonical form for the effective Hamiltonian of the liquid is elaborated. The the structure of the leading singular terms of the density and entropy diameters is analyzed. The peculiarities of the critical behavior of the liquid systems with the Coulombic subsystem are explained.

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