Zatovsky I. Complex substitution in metal-phosphate frameworks

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0512U000023

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

19-12-2011

Specialized Academic Board

26.001.03

Essay

Regularities of formation of crystallinic compounds in multicomponent alkali-phosphate, phosphate-fluoridic and N-phosphate fluxes containing different combinations of polyvalent metals are generalized and analysed. Routes to synthesis and criteria of isolation of complex phosphates with crystal frameworks [MOPO4], [M2(PO4)3], [M(PO4)2], [MPO4], [M3(PO4)4], [M10(PO4)7], [MP2O7] based on alkali and metals of II-VII groups. The studies of new compounds paved the perspectives of their practical application at modern non-linear optical materials, luminophores, ionic conductors. Possibilities of application of phosphates with langbeinite-type frameworks as matrices for immobilization of radioactive isotopes are demonstrated.

Files

Similar theses